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2. The manufacture of ice


2.1 Sea or freshwater

When considering the manufacture of ice on board fishing vessels, seawater will be the natural choice of raw material. When considering whether to use fresh or seawater in land-based plants, the decision will depend on several factors, such as the availability of regular supplies, the location of the ice plant and the intended use of the ice (e.g. for use on board fishing vessels or on shore). Whatever type of water is used, it must be remembered that the resultant ice will come into direct contact with food. For this reason it is essential that the water used is free from contamination that could cause risks to human health or tainting of the fish so that it becomes unacceptable. This implies that the water must be of drinking-water quality and comply with the safety standards laid down by such bodies as the World Health Organization.

The use of seawater ice for chilling fish has been studied for several years and, with the development of suitable small ice machines that can be installed on board fishing vessels, this alternative is becoming more feasible for fishermen. The main advantages of the use of seawater ice are:

However, there are some major disadvantages, such as:

TABLE 2.1
Typical characteristics of flake seawater ice-maker units suitable for small and medium fishing vessels

Capacity1

Cooling requirements

Refrigerant

Remarks

(kg of ice/24 h)

(kcal/h)

550

4 000

R-22

The ice-making unit is equipped with a stainless steel revolving drum evaporator.
This unit can be installed on deck or inside the fish hold. Condensing unit and compressor are located in the engine room. Ice production capacity is based on a water supply temperature of 10 °C and evaporator temperature of -30 °C. It is estimated that a one-day ice production will require a refrigerated storage space of about 1.24 m3.

1 350

7 100

R-22

As above. It is estimated that a one-day ice production will require a refrigerated storage space of about 3.05 m3.

1 950

11 000

R-22

As above. It is estimated that a one-day ice production will require a refrigerated storage space of about 4.4 m3.

4 500

21 434

R-22, or any ozone-friendly refrigerant

The self-contained unit has a pressurized water feed system and a stainless steel evaporator disc for producing subcooled flake ice.
Ice production capacity is based on a water supply temperature of 16 °C and -23 °C evaporator temperature. An optional remote water-cooled condensing unit suitable for use with seawater can be installed (40-80 litres per minute of water consumption at 16 °C).
It is estimated that a one-day ice production will require a refrigerated storage space of about 10.2 m3.

8 000

36 290

As above

The flake ice-maker can be installed on board as a self-contained unit or as a remote unit with a refrigeration plant that can be driven electrically, by diesel or hydraulics. All ice contact surfaces of the unit are stainless steel or corrosion resistant to seawater materials.
Seawater supply for ice-making is delivered to the freezing surface in a pressurized system.
The evaporator suction temperature is -32 °C and seawater supply temperature is 21 °C.
The manufacturer recommends the use of pressurized water delivery and variable speed for on-board installed ice-makers.

10 000

45 363

As above

As above

12 000

54 435

As above

As above

1 Ice production capacities can vary with evaporator and water temperatures, type of refrigerant and ice thickness. Therefore, the above data are the average output of seawater ice leaving the ice-maker at a temperature of -20 °C, under the conditions listed above

The following design factors for on-board seawater ice machines should be considered:

The advantages of having on-board ice machines, especially for fishermen dedicated to the production of fresh fish, can be summarized as follows:

The principal disadvantages are:

The most common type of ice-maker to be installed on board a small fishing vessel would be a flake ice-maker. Table 2.1 gives some characteristics of flake ice-makers capable of producing seawater ice suitable for use on board small- and medium-size fishing vessels.

Table 2.2 gives some typical dimensions for various types of “package” ice machines that, according to manufacturers, are suitable for installation on board fishing vessels. All machines shown are water-cooled models, except for the Coldisc model. Some examples of other machines are given to show how changes in dimensions affect production capacities.

However, in order to use ice at sea it is not necessary to take ice-makers to sea. As has already been indicated, ice can be moved from place to place and is a form of portable refrigeration. This allows ice made in shore-based plants to be taken to sea and used as and when required.

2.2 Types of ice and how they are made

2.2.1 Block ice

Block ice was first manufactured commercially in 1869. It is made by filling metal cans with water and lowering them into a bath of brine (usually sodium or calcium chloride) refrigerated to well below the freezing point of water. The water freezes in the cans and the ice blocks are removed from the cans after several hours of freezing. The cans are immersed in freshwater to release the ice blocks, which are then stored.

TABLE 2.2
Capacities and principal dimensions of various ice-making machines suitable for use on fishing vessels

Type of machine

Capacity

Depth

Width

Height

Weight

(tons US & kg/24 h)

(mm)

(mm)

(mm)

(kg)

Flake ice “Coldisc” front discharge

1.0 t
909 kg

660

520

510

45 machine only

Flake ice, drum type

1.0-2.5 t
909-2 272 kg

965

635

1 118

250

Flake ice, drum type

6.0 t
4 272 kg

1 219

813

1 143

614

Shell ice, tube type, hot gas cycle

11.5 t
1 363 kg

1 372

762

1 555

771

Shell ice, tube type, hot gas cycle

13.0 t
2 727 kg

2 444

762

1 555

1 315

Slush ice

33.3 t
3 000 kg

1 000

650

800

260

Slush ice

23.5 t
3 181 kg

630

580

1 700

390

Slush ice

35.5 t
4 992 kg

1 000

800

1 900

500

Slush ice

27.0 t
6 363 kg

660

1 010

1 700

800

1 Outputs based on ambient of 90 °F (32 °C).
2 Outputs based on ambient of 50 °F (10 °C).
3 Output based on 0 to 1 °C feedwater, prechiller unit recommended.

The production of block ice is a batch operation and, once emptied, the cans are refilled with water and replaced in the brine tank for a further freezing period. Whatever the capacity of the ice-maker for block ice production, a continuous labour force is required to manage all operations, particularly ice harvesting and handling. The main advantages of block ice in comparison with other types of ice are:

The main disadvantages of block ice production are:

Containerized block ice plants are available that house the ice plant, ice store and complete refrigeration and electrical systems inside standard containers. This allows portability, ease of transport by sea and land, better reliability and significantly shorter installation and break-in periods than traditional noncontainerized types. These advantages are important, particularly in remote areas where there is limited refrigeration and maintenance expertise. These units are fitted into standard 40 ft containers, and are easy to install. They only require a levelled foundation and to be under cover for protection against the weather, and they can be built in tropical climates and coastal conditions. Units are available that produce blocks of various sizes from 12.5 to 25 kg. Table 2.3 gives some information on containerized block ice plants.

Figure 2.1 shows the relationship between the thickness of ice produced and the time it takes to freeze in typical block ice production. In general, the thicker the ice block, the longer the freezing time. For example, a 136 kg block will require on average about 36 h of freezing time, in comparison to a 25 kg block that will require on average about 12 h.

TABLE 2.3
Typical characteristics of containerized block ice plants

Ice capacity1
(kg/24 h)

Ice storage capacity
(kg)

Space requirements
(m2)

3 000

6 000

30 (for the container)

5 000

5 000

30 (for the container)

7 500

3 000

30 (for the container)

10 000

none

30 (for the container)

1 Rated capacity at continuous harvest operation. Ice storage temperature is about -5 °C; with an eight-hour freezing cycle.

2.2.2 Rapid block ice

The long time periods required to produce blocks of ice have led to the development of what are known as rapid block ice plants. The aim of these plants is to produce blocks of ice in a few hours. Instead of ice cans being immersed in a brine tank, the water in the can is frozen by a refrigerant which is circulated through the outer jacket of each can, as well as through a piping system located inside the cans. Ice is formed simultaneously on all refrigerated surfaces in contact with the water. After completion of the freezing cycle, the blocks are quickly removed from the can by means of a hot gas defrost and released by gravity. The main advantages of rapid block ice-makers are their reduced space requirements in comparison with traditional block ice-makers and the relatively easy operations for starting and stopping, which take a short time in comparison with the traditional block ice-makers. However, rapid block ice plants are generally more expensive to purchase, run and maintain than conventional block ice plants and their use in the fishing industry is limited.

FIGURE 2.1 Relationship between the thickness of ice produced and the freezing time required, in a typical production of traditional freshwater block ice

Source: Hernandez Fuentes, 1995.

2.2.3 Flake ice

Flake ice can be defined as dry and subcooled small ice in flat pieces having an irregular wafer shape.

This type of small ice is manufactured by spraying or pouring water onto a refrigerated surface, often in the form of a cylinder or drum. The water freezes on the surface and forms thin layers of ice (2-3 mm thick). A scraper removes the subcooled ice, which breaks into small pieces resembling splinters of glass. These pieces of ice usually fall from the drum directly into a refrigerated compartment for storage. The cooled cylinder can rotate either in a vertical or horizontal plane.

A second type of flake ice-maker of particularly compact size, specifically designed for on-board ice-making is illustrated in Figure 2.2. Produced by North Star Ice Equipment Corporation, it departs from the normal drum style configuration and instead produces flake ice on a rotating subcooled evaporator disc. Ice is then harvested from both sides of the disc by adjustable ice scrapers. It would appear that this machine could be used in fish holds of boats 12 to 16 m long in some artisanal fleets considering its compact size and light weight. On smaller vessels it is likely to be installed on deck. The technical characteristics of this type of ice-maker are shown in Table 2.4.

FIGURE 2.2 Coldisc ice machine

Source: North Star Ice Equipment Corp., Seattle, Washington, USA.

A variation on flake ice is known as chip ice. Chip ice is manufactured by flowing water inside the ice-making cylinder, which is surrounded by an evaporating coil. The water is frozen inside the cylinder at an evaporator temperature of -12 to -30 °C and removed with an auger revolving inside the cylinder and pushing the ice upwards. In the upper part of the cylinder the ice is pressed, frozen further and ejected through the top of the cylinder. Chip ice has a temperature of -0.5 °C and an average thickness of 7-8 mm.

When installed on board fishing vessels, flake ice machines are often mounted on the deck so that the ice produced is discharged directly into the fish hold via a small hatch provided for this purpose. Most drum-type ice-makers designed for fishing vessels have an ice discharge port directly below the drum centre, making installation over a dedicated hatch possible. Depending on the machine, its location on deck and manufacturers’ recommendations, some form of shielding or cabinet may be necessary to protect control panels or other parts of the unit from the environment.

The below-deck installation is generally more problematic as most machines rely on gravity after removal of ice from the drum to put ice in the storage bins. This would require a fairly large fish hold with sufficient height to the deckhead to provide room for the machinery installation and enough height to allow gravity feed to a collection area or storage pens. Flake or shell ice machines may require the installation of conveyors or augers in larger vessels, though in the majority of instances, crew with shovels will transfer the ice produced to storage pens as needed.

TABLE 2.4
Typical characteristics of some flake ice-makers

Ice capacity1

Cooling requirements

Refrigerant

Remarks

(kg/24 h)

(kcal/h)

1 000

4 760

R-22 or any suitable ozone-friendly refrigerant

Water supply: 42 litres per hour at 16 °C and -23 °C evaporator temperature.
Ice thickness: 1.5 mm.
Size of the unit without ice storage: H (510 mm) × W (520 mm) × L (660 mm).
Unit weight: 45 kg. (Disc unit)

2 250

10 590

As above

Water supply: 102 litres per hour at 16 °C and -23 °C evaporator temperature.
Ice thickness: 1.5 mm.
Size of the unit without ice storage: H (1 065 mm) × W (685 mm) × L (865 mm).
Unit weight: 165 kg. An optional remote water-cooled condensing unit suitable for installation on board fishing vessels can be fitted, with a seawater supply at 16 °C of 1 200 litres per hour.
Standard operating temperature of condenser: 35 °C

4 500

21 434

As above

Water supply: 204 litres per hour at 16 °C and -23 °C evaporator temperature.
Ice thickness 1.5 mm.
Size of the unit without ice storage: H (1 065 mm) × W (865 mm) × L (865 mm).
Unit weight: 225 kg.
An optional remote water-cooled condensing unit suitable for installation on board fishing vessels can be fitted, with a seawater supply at 16 °C of 2 400-4 800 litres per hour. Standard operating temperature of condenser: 35 °C

9 000

42 867

As above

Water supply: 420 litres per hour at 16 °C and -23 °C evaporator temperature.
Ice thickness 1.5 mm. Size of the unit without ice storage: H (1 065 mm) × W (1 120 mm) × L (865 mm).
Unit weight: 300 kg.
An optional remote water-cooled condensing unit suitable for installation on board fishing vessels can be fitted, with a seawater supply at 16 °C of 4 800-9 600 litres per hour. Standard operating temperature of condenser: 35 °C

1 For large ice-makers it is recommended that in tropical areas, with water temperatures over 21 °C, feed water should be chilled in a separate chiller (to cool the water to a range of 4.4 to 7.2 °C) to avoid significantly lower ice outputs and higher energy consumption. See Figure 2.3 for details on the relationship between feed-water temperature and required tonnes of refrigeration (1 tonne of refrigeration = 3 024 kcal/h = 12 000 Btu/h).

The main advantages of flake ice are as follows:

FIGURE 2.3 Relationship between make-up water temperature and tonnes of refrigeration required for the production of 907 kg of flake ice per 24 h

However, flake ice has a number of disadvantages in comparison to block ice. For example:

As with block ice plants, flake ice plants can be containerized into 20 and 40 ft containers, depending on the capacity of the ice-makers and ice storage systems required. These units can be made so that they simply need to be connected to a power and water supply and with some modifications can be installed on board very large fishing vessels. However, these shipboard units are outside the size range of vessels examined in this publication. Large capacity models for freshwater flake ice production are also available for onshore installations, making between 10 and 100 tonnes of ice with multicontainer systems (these models have the complete icemaker unit mounted on top of the insulated container which is used as an ice store). Technical specifications and characteristics of some typical containerized flake and chip ice plants are given in Table 2.5.

TABLE 2.5
Typical technical features of containerized flake/chip ice plants

Standard containerized flake/chip ice plants

Ice capacity
(kg/24 h)

Ice storage capacity

Container

Remarks

3 000

13 m3 /
5 000 kg

20 ft

Space requirements: 15.74 m2.
Standard operating conditions: ambient temperature: 35 °C and freshwater feed temperature: 25 °C; power: 380 volts/3 phase/50 or 60 Hz; water supply: 3 000 litres/24 h. Refrigerant used: R-22 or R-717

5 000

13 m3 /
5 000 kg

20 ft

Space requirements: 15.74 m2.
Standard operating conditions: ambient temperature: 35 °C and freshwater feed temperature: 25 °C; power: 380 volts/3 phase/50 or 60 Hz; water supply: 5 000 litres/24 h. Refrigerant used: R-22 or R-717

10 000

13 m3 /
5 000 kg

20 ft

Space requirements: 15.74 m2.
Standard operating conditions: ambient temperature: 35 °C and freshwater feed temperature: 25 °C; power: 380 volts/3 phase/50 or 60 Hz; water supply: 10,000 litres/24 h. Refrigerant used: R-22 or R-717

5 000

37m3 /
15 000 kg

40 ft

Space requirements: 30 m2.
Standard operating conditions: ambient temperature: 35 °C and freshwater feed temperature: 25 °C; power: 380 volts/3 phase/50 or 60 Hz; water supply: 5,000 litres/24 h. Refrigerant used: R-22 or R-717

7 500

37 m3 /
15 000 kg

40 ft

Space requirements: 30 m2.
Standard operating conditions: ambient temperature: 35 °C and freshwater feed temperature: 25 °C; power: 380 volts/3 phase/50 or 60 Hz; water supply: 7 500 litres/24 h. Refrigerant used: R-22 or R-717

10 000

37 m3 /
15 000 kg

40 ft

Space requirements: 30 m2.
Standard operating conditions: ambient temperature: 35 °C and freshwater feed temperature: 25 °C; power: 380 volts/3 phase/50 or 60 Hz; water supply: 10 000 litres/24 h. Refrigerant used: R-22 or R-717

3 000

20 m3 /
8 000 kg

15 m3

Type of container: 40 ft. Space requirements: 30 m2.
Standard operating conditions: ambient temperature: 35 °C and water feed temperature: 25 °C; power: 380 volts/3 phase/50 or 60 Hz; water supply: 10 000 litres/24 h. Water-cooled condensers for seawater can be installed. Refrigerant used: R-22 or R-717

5 000

20 m3 /
8 000 kg

15 m3

Type of container: 40 ft. Space requirements: 30 m2.
Standard operating conditions: ambient temperature: 35 °C and water feed temperature: 25 °C; power: 380 volts/3 phase/50 or 60 Hz; water supply: 10 000 litres/24 h. Water-cooled condensers for seawater can be installed. Refrigerant used: R-22 or R-717

10 000

20 m3 /
8 000 kg

15 m3

Type of container: 40 ft. Space requirements: 30 m2.
Standard operating conditions: ambient temperature: 35 °C and water feed temperature: 25 °C; power: 380 volts/3 phase/50 or 60 Hz; water supply: 10 000 litres/24 h. Water-cooled condensers for seawater can be installed. Refrigerant used: R-22 or R-717

2.2.4 Compacted blocks of small ice

When there is a need for ice supplies to be transported over long distances, or there are preferences in certain fisheries for block ice, it is feasible to produce blocks from small or flake ice using block-compacting machines. These machines press small ice (flake or chip ice) into blocks of standard sizes and can be easily installed in shore-based small ice plants. These compacted blocks of small ice can be used on board fishing vessels giving the advantages of conventional block ice. They could be particularly suitable in tropical developing fisheries where ice-melt rates are high and fishermen are used to handling blocks of ice from older ice plants. The compacted blocks of small ice are easier to break into small pieces when needed.

2.2.5 Slush ice

One type of ice plant well suited for use on board fishing vessels is the slush ice machine that produces subcooled ice crystals. When mixed with water, the crystals allow slurry to be pumped easily by flexible hoses to wherever it is required on the boat. This ice acts in a similar manner to CSW when in slurry form, and as such can be used in CSW tanks or fish holds. In slightly less liquid form it can also be used to bulk pack fish in tote boxes. Figure 2.5 shows in diagrammatic form how this type of installation may be installed in fishing vessels of appropriate size.

Slush ice is a mixture of ice crystals in water and water slurry. The ice is formed by freezing ice crystals out of a weak brine solution in a tube-in-tube heat exchanger, also called a scraped-surface heat exchanger. Water is frozen as tiny round/ellipsoid crystals (about 0.2 to 1.3 mm diameter) on the inner-tube surface and a rotary screw conveyor moves the ice crystals out of the heat exchanger into a storage tank with water. The resulting mixture of ice and water (slush ice) can be pumped from the storage tanks through piping or hoses to the fish-chilling area or directly to an insulated container. The density and fluidity of slush ice can be adjusted by regulating the amount of water added, so that they can be tailored to different applications.

The advantages claimed for slush ice for chilling fish are as follows (see also Table 2.6):

FIGURE 2.4 Typical plant installation (24 tonnes/day)

Source: Sunwell Engineering Co. Ltd, Woodbridge, Ontario, Canada.

FIGURE 2.5 Schematic of slush ice use on fishing boats

Source: Brontec USA Inc.

TABLE 2.6
Typical specifications for a twin-tube slush ice-maker

Capacity
(kg/24 h)

Power requirements

Remarks

5 000, based on feed water at 10 °C and 3% NaCl concentration

220 volts, AC, 3 phases, 50/60 Hz; 9.6 kW

Two ice-generator tubes, 316 stainless steel. R-22 as refrigerant. Two compressors of 8 610 kcal/h capacity and -11 °C at suction and 38 °C at condensing. Two seawater-cooled condensers of 1 380 litres per hour capacity each, with standard operating condensing temperature of 38 °C. Seawater supply temperature of 24 °C. Frame construction: stainless steel tube. Dimensions of unit: W: 100 mm; L: 660 mm; H: 1 700 mm

Note: currently, models of slush ice-makers from 2.5 to 24 tonnes per 24 h capacity are available, both as self-contained units or as remote units, with separated refrigeration systems for on board installation.

FIGURE 2.6 Chilling curve of whole cod (1-2.2 kg/piece) in pumpable slush ice (seawater liquid ice) compared to flake ice

Since the “raw material” for ice production is a brine solution (3-5 percent NaCl), seawater can be used for slush ice manufacture. This allows units to be installed on board fishing vessels. The commercial application of slush ice on board industrial purse seiners has been tested for chilling small pelagics, with good results. The slush ice has been used to enhance the traditional RSW system on board purse seiners, and improve the chilling process by significantly shortening the cooling period, from 7-20 h on regular RSW to about one hour. As can be seen from Figure 2.6, the cooling time for fish in slush ice is considerably shorter than in flake ice and is comparable with cooling times encountered with CSW.

2.2.6 Chilled seawater

CSW as a cooling medium is becoming much more common in small fishing vessels. For instance, boats as small as 32 ft (9.75 m) length overall are using this system to preserve high-value catch in top condition after capture. Overall temperature control in the CSW tanks is achieved by the addition of ice to lower seawater temperature and that of the catch as it is added during the trip. To prevent temperature stratification in CSW tanks, two basic systems are used, one is compressed air, also known as the “champagne” system, and the other is CSW recirculation by pump. These are illustrated in Figure 2.7.

2.2.7 Refrigerated seawater

RSW systems have an on-board refrigeration plant to chill the seawater rather than using melting ice. In addition, they need pumps, piping and filters for circulation of the RSW in the tanks or holds. In normal practice this system requires a dedicated power plant, such as a diesel or diesel electric generator, providing direct power or electricity to operate the electric motors for refrigeration compressors and circulation pumps, depending on the type of drive motors used.

FIGURE 2.7 CSW tanks with the “champagne” compressed air system and recirculation of water

Two basic systems are used for RSW cooling of products: one involves simply immersing the catch in filled RSW tanks; the second system does not use tanks but sprays chilled water over shelved catch.

When filling RSW tanks in the hold with clean water that is then refrigerated, some boats will load ice into the tanks prior to filling with water. This saves time and alleviates some of the load on the refrigeration system by pre-chilling the water. Figure 2.8 illustrates a typical RSW spray system as installed in vessels of the Pacific northeast coast. Tanks for RSW are similar in arrangement to CSW tanks, the principal difference is in the installation of a refrigeration unit with its power supply and a much better filter system for the recirculated water.

FIGURE 2.8 RSW spray system

Source: Integrated Marine Systems Inc., Pt Townsend, WA, USA.

Recent developments in hydraulic systems have now made it possible to run a refrigeration compressor using hydraulic power from a power take off (PTO) from the boat’s main engine. This has been developed utilizing load-sensing pumps, which, when set, maintain a constant flow regardless of engine speed. This allows a refrigeration compressor to run at constant speed whether the engine is idle or running at full speed. These pumps go to standby mode when there is no demand for hydraulic flow, and only small amounts of power are consumed in this mode. However, if the main engine is idling when the compressor cuts in there is a considerable power demand. For this reason engineers recommend that the main engine should have very good power reserves at low or idle speeds.

TABLE 2.7
Montreal Protocol provisions regarding ozone-depleting chemicals

Chemical compound

Remarks

Group I - CFCs
R-11; R-12; R-113; R-114, R-115, R-502

Gradual reduction over the 1990s.
Full replacement by the year 2000 in developed countries and by the year 2010 in developing countries.

Group II - Halons
Halon 1211; halon 1301; halon 2402 and carbon tetrachloride

Gradual reduction over the 1990s.
Full replacement by the year 2000 in developed countries. Developing countries have a ten-year grace period.

Group III
Methyl chloroform

Gradual reduction over the 1990s.
Full replacement by the year 2005 in developed countries. Developing countries have a ten-year grace period.

Note: all Protocol provisions came into force on 1 January 1989 and were revised in 1990.

TABLE 2.8
Atmospheric lifetimes and ozone depletion potential of some halogenated hydrocarbons

Chemical compound

Lifetime
(years)

Ozone depletion potential

HFC: R-32 (CH2F2)

6.7

0

HFC: R-125 (CF3CF2H)

26

0

HFC: R-134a (CF3CFH2)

14

0

HCF: R-143a (CF3CH3)

40

0

HCFC: R-22 (CHF2Cl)

14

0.047

CFC: R-11 (CFCl3)

60

1

CFC: R-12 (CF2Cl2)

105

0.95

2.3 Refrigerants and their environmental impact

Chemicals used as refrigerants, known as chlorofluorocarbons (CFCs), are known to have adverse effects on the earth’s stratospheric ozone layer. As a consequence, international efforts are being made to phase out most of the CFCs or halogenated hydrocarbons from commercial use (see Table 2.7). A number of more environmentally acceptable alternatives are being proposed, such as R-22, ammonia (R-717), HP-62 and hydrofluorocarbons (HFCs) and hydrochlorofluorocarbons (HCFCs), see Table 2.8. Examples of the new HFCs and HCFCs are as follows:

TABLE 2.9
Brief technical data of some refrigerants used in fisheries

Refrigerant

Evaporating pressure at -15 °C

Condensing pressure at 30 °C

Boiling point at 1.013 bar

(lb/sq. in)

(lb/sq. in)

(°C)

R-12 (CCl2F2)

11.8

93.2

-29.8

R-22 (CHClF2)

28.3

159.8

-40.8

R-717 (ammonia)

19.6

154.5

-33

The main technical characteristics of HFCs and HCFCs are:

With regard to the refrigerants most widely used in fisheries, R-12, R-22, R-502 and ammonia (R-717) are the leading products, see Table 2.9. However, with the ban on CFCs by the year 2000 in developed countries, most of the existing refrigeration plants using CFCs will be facing serious problems in the conversion from R-12 and R-502 to other refrigerants. From the engineering point of view, the conversion of refrigeration plants to use alternate refrigerants is possible in some cases. For example, a brief analysis for converting R-12 refrigeration plants into R-22 plants could show the following:

2.4 Safety observations

Currently R-717 (ammonia) is the main alternative refrigerant for CFCs used commercially for large-size ice plants, with the advantage that this chemical has no detrimental effect on the ozone layer. Although R-717 is considered toxic and corrosive, the sharp odour and irritating properties also serve as a warning when leaks develop. It is rated as being lethal, or capable of producing serious injuries to humans at concentrations of 0.5 to 1 percent for exposures of a few to 30 minutes. This is particularly true on board boats, where clouds of R-717 are produced by large gas leaks in enclosed areas, which in some cases could trap and cause serious injuries or death to personnel before they could evacuate the refrigeration section. In addition, R-717 can be subject to explosion and fire when combined with certain amounts of air or oxygen. The smallest percentage of gas/vapour that will make an ignitable air-vapour mixture for R-717 is 15.5 percent by volume in air. If there is less gas in the mixture, it is too lean to burn. However, on board, in some areas such as refrigerated process or storage areas, which can be considered as unusually tight locations, the release of R-717 in large quantities can result in an explosion. Therefore, there are health hazards associated with the use of R-717 and skilled labour is required to operate and maintain R-717 refrigeration plants.

On board large fishing vessels, R-717 refrigeration machinery should be located in a separate refrigeration section (vapour-proof type compartment equipped with leakage/fire alarms systems). The refrigeration section should have two exits, one of them with direct access to the open deck. The section should be provided with emergency ventilation with a capacity of 30 times the air volume per hour and be equipped with remote-controlled emergency water sprinklers. The exits from the refrigeration section should be equipped with emergency water curtains to prevent further leakage of ammonia outside the room. The primary function of the sprinkler systems is to limit the spread of gas, to protect personnel in these areas and maintain escape routes. Additionally, water sprinklers may extinguish fires in the refrigeration room and control the amount of heat produced. Suitable pressurized air breathing apparatus should be available at both exits from the refrigeration section and be located within easy reach.


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